Phosphorus
Functions
The formation and maintenance of the skeleton, bones and teeth largely depends on phosphorus: 80 % of body‘s phosphorus is located in the bones and teeth, co-precipitated with calcium in the hydroxy-apatite complex. The remaining 20 % is contained in nucleotides such as ATP, nucleic acids, in phospholipids and other phosphorylated compounds. The outstanding importance of phosphorus is therefore also reflected in its metabolic functions: regeneration of energy supply, transfer of fatty acid, formation of amino-acids, cell membrane bilayer and acid-base buffer. Phosphorus is also important in fertility and reproduction as well as in milk secretion, eggshell formation and muscle tissue formation.
The formation and maintenance of the skeleton, bones and teeth largely depends on phosphorus: 80 % of body‘s phosphorus is located in the bones and teeth, co-precipitated with calcium in the hydroxy-apatite complex. The remaining 20 % is contained in nucleotides such as ATP, nucleic acids, in phospholipids and other phosphorylated compounds. The outstanding importance of phosphorus is therefore also reflected in its metabolic functions: regeneration of energy supply, transfer of fatty acid, formation of amino-acids, cell membrane bilayer and acid-base buffer. Phosphorus is also important in fertility and reproduction as well as in milk secretion, eggshell formation and muscle tissue formation.
Main sources
Dicalcium phosphate dihydrate
Dicalcium phosphate anhydrous
Monodicalcium phosphate
Monocalcium phosphate
Phosphate containing calcium carbonate
Magnesium phosphate
Calcium-magnesium phosphate
Sodium-calcium-magnesium phosphate
Monoammonium phosphate
Monosodium phosphate
Quality and selection parameters
Depending on the chemical form, the chemical purity and the production process it has been demonstrated by “in vivo” experiments (bone mineralisation) that the relative biological availability (RBV) of feed phosphates can vary between 80% and 100% (available phosphorus). Other “in vivo” experiments determine the phosphorus absorbed in the intestinal tract (digestible phosphorus) mainly for pigs. “In vitro“ methods (solubility) are less accurate but can give an approximation (soluble phosphorus in ammonium citrate or in 2 % citric acid).
Relevant criteria for the selection of phosphorous sources are total phosphorus content, available/digestible phosphorus content, calcium/phosphorus ratio, solubility, pH, level of undesirable substances, physical form (powder / granulated) and apparent density.
Relevant criteria for the selection of phosphorous sources are total phosphorus content, available/digestible phosphorus content, calcium/phosphorus ratio, solubility, pH, level of undesirable substances, physical form (powder / granulated) and apparent density.
Analytical methods
Total phosphorous | quinoline, Dir. 77/535/EEC |
Phosphomolybdate | gravimetric |
Soluble phosphorus | in 2 % citric acid : in alkaline ammonium citrate (Petermann) in water |
Calcium | atomic absorption spectrometry X-ray fluorescence |
Sodium | atomic absorption spectrometry X-ray fluorescence |
Magnesium | spectra photometric atomic absorption X-ray fluorescence |
Moisture |
acetone wash method oven drying method |
Grade of hydration | X-ray diffraction thermo-gravimetric method |
Conversion factors
P x 2.291 = P2O5 | Ca x 1.39 = CaO | Mg x1.66 = MgO |
P2O5 x 0.437 =P | CaO x 0.715 = Ca | MgO x 0.6 = Mg |